

@mastersthesis {6281,
	title = {Confocal {Microscopy} of {Jammed} {Matter}: {From} {Elasticity} to {Granular} {Thermodynamics}},
	year = {2013},
	note = {3557007},
	school = {New York University},
	type = {phdPh.{D}.},
	address = {Ann Arbor},
	abstract = {Packings of particles are ubiquitous in nature and are of interest not only to the scientific community but also to the food, pharmaceutical, and oil industries. In this thesis we use confocal microscopy to investigate packing geometry and stress transmission in 3D jammed particulate systems. By introducing weak depletion attraction we probe the accessible phase-space and demonstrate that a microscopic approach to jammed matter gives validity to statistical mechanics framework, which is intriguing because our particles are not thermally activated. We show that the fluctuations of the local packing parameters can be successfully captured by the recently proposed {\textquoteright}granocentric{\textquoteright} model, which generates packing statistics according to simple stochastic processes. This model enables us to calculate packing entropy and granular temperature, the so-called {\textquoteright}compactivity{\textquoteright}, therefore, providing a basis for a statistical mechanics of granular matter. At a jamming transition point at which there are formed just enough number of contacts to guarantee the mechanical stability, theoretical arguments suggest a singularity which gives rise to the surprising scaling behavior of the elastic moduli and the microstructure, as observed in numerical simulations. Since the contact network in 3D is typically hidden from view, experimental test of the scaling law between the coordination number and the applied pressure is lacking in the literature. Our data show corrections to the linear scaling of the pressure with density which takes into account the creation of contacts. Numerical studies of vibrational spectra, in turn, reveal sudden features such as excess of low frequency modes, dependence of mode localization and structure on the pressure. Chapter four describes the first calculation of vibrational density of states from the experimental 3D data and is in qualitative agreement with the analogous computer simulations. We study the configurational role of the pressure and demonstrate that low frequency modes become progressively localized as the packing density is increased. Another application of our oil-in-water emulsions serves to mimic cell adhesion in biological tissues. By analyzing the microstructure in 3D we find that a threshold compression force is necessary to overcome electrostatic repulsion and surface elasticity and establish protein-mediated adhesion.},
	keywords = {0605:Physics, 0611:Condensed matter physics, Condensed matter physics, Density of states, Emulsions, Granocentric, Jamming, Packing, Physics, Pure sciences, Tissue},
	url = {http://search.proquest.com/docview/1332708464?accountid=14270},
	author = {Jorjadze, Ivane}
}
